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Hafnium tetrachloride : ウィキペディア英語版
Hafnium tetrachloride

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Hafnium(IV) chloride is the inorganic compound with the formula HfCl4. This colourless solid is the precursor to most hafnium organometallic compounds. It has a variety of highly specialized applications, mainly in materials science and as a catalyst.
==Preparation==
HfCl4 can be produced by several related procedures:
*The reaction of carbon tetrachloride and hafnium oxide at above 450 °C;
:HfO2 + 2 CCl4 → HfCl4 + 2 COCl2
*Chlorination of a mixture of HfO2 and carbon above 600 °C using chlorine gas or sulfur monochloride:
:HfO2 + 2 Cl2 + C → HfCl4 + CO2
*Chlorination of hafnium carbide above 250 °C.〔Elinson, S. V. and Petrov, K. I. (1969) ''Analytical Chemistry of the Elements: Zirconium and Hafnium.'' 11.〕

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